With very few exceptions, becoming a non-commissioned officer (NCO) or petty officer in the U.S. Armed Forces is accomplished by progression through the lower enlisted ranks. However, unlike promotion through the lower enlisted tier, promotion to NCO is generally competitive. NCO ranks begin at E-4 or E-5, depending upon service and are generally attained between three and six years of service. Junior NCOs function as first-line supervisors and squad leaders, training the junior enlisted in their duties and guiding their career advancement.
As a general rule of thumb, anything over an 85 on the ASVAB will qualify you for nearly any position in the armed forces. But there are slight breakdowns within each score. For example, in order to qualify for Surveillance and Communications (SC) in the Army, Word Knowledge, Paragraph Comprehension, Arithmetic Reasoning, Auto & Shop and Mechanical Comprehension all require high marks. Though scoring an 85 or above would guarantee you scored in a high enough percentile to qualify for SC.

The Armed Services Vocational Aptitude Battery (ASVAB test--also known as the AFQT (Armed Forces Qualification Test). This is the score used by the recruiter to determine a potential recruit’s enlistment eligibility, assign a recruit to a military jobs, and aid students in career exploration. The AFQT is actually a subset of the ASVAB - only with scores of four of the ten test sections calculated.
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